Cations and Catalysis

Cations in charge: magnesium ions in RNA folding and catalysis.

The role of cations in avian liver phosphoenolpyruvate carboxykinase catalysis. Activation and regulation.

The activation of the avian liver phosphoenolpyruvate carboxykinase catalyzed reversible decarboxylation of oxalacetate by Mn2+ has been studied. The Mn2+ facilitates the interaction of oxalacetate to the enzyme. At saturating ITP and oxalacetate concentrations, Mn2+ has a Km = 2 microM. The cation Mg2+ can substitute for Mn2+ with 50% Vmax in the oxalacetate decarboxylation and 2% Vmax in the ...

O-atom transport catalysis by atomic cations in the gas phase: reduction of N2O by CO.

Atomic cations (26), M+, have been shown to lie within a thermodynamic window for O-atom transport catalysis of the reduction of N2O by CO and have been checked for catalytic activity at room temperature with kinetic measurements using an inductively-coupled plasma/selected-ion flow tube (ICP/SIFT) tandem mass spectrometer. Only 10 of these 26 atomic cations were seen to be catalytic: Ca+, Fe+,...

The chemistry of amine radical cations produced by visible light photoredox catalysis

Amine radical cations are highly useful reactive intermediates in amine synthesis. They have displayed several modes of reactivity leading to some highly sought-after synthetic intermediates including iminium ions, α-amino radicals, and distonic ions. One appealing method to access amine radical cations is through one-electron oxidation of the corresponding amines under visible light photoredox...

Direct observation of hexamethylbenzenium radical cations generated during zeolite methanol-to-olefin catalysis: an ESR study.

The generation of hexamethylbenzenium radical cations as the key reaction intermediate in chabazite-type molecular sieve acids (i.e., H-SAPO-34 and H-SSZ-13) during the methanol-to-olefin process has been directly evidenced by ESR spectroscopy.